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 | | From: | Lewis Mammel | | Subject: | Re: too much information! | | Date: | Sat, 15 Jan 2005 05:38:13 GMT |
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Mike wrote: > > John Baez wrote: > > [snip] > > > > But, I wasn't trying to explain this stuff in detail - just > > compute the amount of information in a raindrop! > > [snip] > > Now that you "know" the amount of information, can you use it in any > way to replicate the rain drop?
Well, you would have to have the actual information, not just know the amount of it! Remember this would be 1E24 bits - a trillion terabits. This is the problem of Maxwell's Demon in spades.
Maxwell's Demon is an imagined demon of whatever sort that operates a microscopic portal between two chambers of a gas. It can cause one side to get hotter by opening the portal to let through fast molecules in one direction, and slow molecules in the other direction, creating a violation of the Second Law.
It is Maxwell's Demon that stimulated the thought about the relationship between information and entropy. The original thought was that the demon would have to create more entropy than he destroyed in carrying out its project, so an "entropy cost" of information was postulated.
In the Quantum view, there are many reasons to think that every raindrop at the same temperature and pressure, and the same number of molecules, and other external conditions, is equivalent to every other.
Certainly, there is no question of specifying the velocity and position of the molecules. A lot of the energy of the drop is tied up in hydrogen bonds and dissociation, which depend on the motion of the electrons.
There's interesting info about this on the net if you search for "water" "molecule" "structure" and the like.
Remember from basic chemistry that 1 in ten million of each HOH is dissociated. ( 1E-7 provides the "7" in the pH of water. ) I read that the average lifetime of an intact HOH is 1 millisecond. Of course, these dissociations and reassociations are quantum events, subject to uncertainty, so I think we can safely say that there is no way to "prepare" the quantum state of a water droplet in any meaningful sense.
Lew Mammel, Jr.
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 | | From: | David Bernier | | Subject: | Re: too much information! | | Date: | Sat, 15 Jan 2005 09:26:26 -0500 |
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 | Lewis Mammel wrote: > > Mike wrote: > >>John Baez wrote: >> >>[snip] >> >>>But, I wasn't trying to explain this stuff in detail - just >>>compute the amount of information in a raindrop! >> >>[snip] >> >>Now that you "know" the amount of information, can you use it in any >>way to replicate the rain drop? > > > Well, you would have to have the actual information, not just > know the amount of it! Remember this would be 1E24 bits - > a trillion terabits. This is the problem of Maxwell's Demon > in spades. > > Maxwell's Demon is an imagined demon of whatever sort that > operates a microscopic portal between two chambers > of a gas. It can cause one side to get hotter by opening > the portal to let through fast molecules in one direction, > and slow molecules in the other direction, creating a violation > of the Second Law. > > It is Maxwell's Demon that stimulated the thought about the > relationship between information and entropy. The original > thought was that the demon would have to create more entropy > than he destroyed in carrying out its project, so an "entropy > cost" of information was postulated. > > In the Quantum view, there are many reasons to think that > every raindrop at the same temperature and pressure, and > the same number of molecules, and other external conditions, > is equivalent to every other. [...]
In quantum theory, a state is a linear composition of eigenstates (say for the hydrogen atom).
From what I've read on the Internet, the coefficients are complex numbers (and there are continuum many of these).
Naively, it would take about countably many bits to represent a state vector...
Is that nonsense?
David Bernier
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 | | From: | Lewis Mammel | | Subject: | Re: too much information! | | Date: | Sat, 15 Jan 2005 18:26:44 GMT |
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David Bernier wrote: > > Lewis Mammel wrote: > > > > Mike wrote: > > > >>John Baez wrote: > >> > >>[snip] > >> > >>>But, I wasn't trying to explain this stuff in detail - just > >>>compute the amount of information in a raindrop! > >> > >>[snip] > >> > >>Now that you "know" the amount of information, can you use it in any > >>way to replicate the rain drop? > > > > > > Well, you would have to have the actual information, not just > > know the amount of it! Remember this would be 1E24 bits - > > a trillion terabits. This is the problem of Maxwell's Demon > > in spades. > > > > Maxwell's Demon is an imagined demon of whatever sort that > > operates a microscopic portal between two chambers > > of a gas. It can cause one side to get hotter by opening > > the portal to let through fast molecules in one direction, > > and slow molecules in the other direction, creating a violation > > of the Second Law. > > > > It is Maxwell's Demon that stimulated the thought about the > > relationship between information and entropy. The original > > thought was that the demon would have to create more entropy > > than he destroyed in carrying out its project, so an "entropy > > cost" of information was postulated. > > > > In the Quantum view, there are many reasons to think that > > every raindrop at the same temperature and pressure, and > > the same number of molecules, and other external conditions, > > is equivalent to every other. > [...] > > In quantum theory, a state is a linear composition of > eigenstates (say for the hydrogen atom). > > From what I've read on the Internet, the coefficients are complex > numbers (and there are continuum many of these). > > Naively, it would take about countably many bits to > represent a state vector... > > Is that nonsense?
Here's from Schoedinger, Statistical Thermodynamics ( 1944 ) :
We shall always regard the state of the assembly as determined by the indication that system No. 1 is in state, say l1, No. 2 in state l2, ..., No. N in state lN. We shall adhere to this, although the attitude is altogether wrong. For a quantum-mechanical system is not in this or that state to be described by a complete set of commuting variables chosen once and for all. [ Noooooooo, Dear Friends! ( sorry ) ] To adopt this view is to think along severely 'classical' lines. With the set of states chosen, the individual system can at best, be relied upon as having a certain probability amplitude, and so a certain probability, of being, on inspection, found in state No.1 or No.2 or No.3 etc. [ your suggestion ] I said: at best a probability amplitude. Not even that much of determination of the single system need there be. ****** Indeed, there is no clear-cut argument for attributing to ****** ****** the single system a 'pure state' at all. ******
The 'nonpure states" are expressed by a density matrix, which allows for a sort of mixture of states. An example I like is the problem of expressing the state of a Boron atom, which has configuration 1s2 2s2 2p1. Any combination of 2p state amplitudes has an orientation, so there is no pure spherically symmetric 2p state. The density matrix allows for the specification of a 'mixed state' which has no preferred orientation.
Well, that's about as much as I can say about it.
Lew Mammel, Jr.
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